&ytodothisiisfullyquantummeicalallowsstiststoexploreiesofmatterthatarerelevaypesofmaterials(forexample,solid-statemetaloxides)overwhichitisdifficulttoexertthesamedegreeofpretrola。Inicgasesitisnowpossibletolookatatomsiesindividuallyaheyaredoingasgesaremadetotheire。
Itispossibletoexplorethislimewithmakindsofatoms,andtobuildplicatedtrappingstructuresusinglight。Theideaofusingsto‘simulate’otherquantumsystemsisatareaofresearch。Itallowsexplorationofplexproblemsthatotbesolvedinotherectedtoleadtoaandingofmaterialsandstructuresthataeshelpiandandevendesigsthatwillbeusedforapplissuchasdatasteforagiagingmaesforhealthcare,orevenfriotorsforlevitatingtrains。
Ultrafast
Lightpulsesbeextremelybrief。Iatedthattheybeasshortasasiheopticalfield。Fhtinthevisibleregiorum,that’sabout2fs。Fhtiremeultraviion,whichisthandhigherfrequeionsbemuchshorter。Theshortestyetmeasuredislessthan100as(10-18s)long。Thesearetlytheshortestpulsesthattrollablygehoughweobserveeventsthathappenonamuescalebymeansofparticlecolliders)。AndwiththeadventofburstsoflightintheX-rayregiorum,ectthateveimescalesarepossible。
&hesenumbersaresomind-bogglinglysmall,itishelpfultoputthemiheageoftheuniverseisapproximately5×1017s。Thustheratioofoheageoftheuniverseisapproximatelythesameastheratioofooonesed。Ortoputitinaneitext,ifthenatioheUSisequivalehewouldbeequivaleosethisscale,asiosedisvirtuallyworthless。
WhatsortofthingsonthistimesChapter4,Iintroducedasimplemodelofanatom—calledtheBohrmodel—irons‘orbit’anatomiucleus,attractedtoitbyeleuchthesamelatheSun,attractedbygravitatioimetakeheseorbitsforsimpleatoms(thatis,thosewithorons)isabout150as。Soifwewanttolookatthismotioousepulsesshorterthanthis,sowedon’tjustseeablur。
Theideaofthestroboscopeistheooourstory,sinceavariantisusedbyresearcherstodaytolookatthereallyspeedygesthatgoonatthefuallevelofatomsandmolethisapplithelightpulsesfromalaseraresplitintotwo(ormore)parts,withadelayiweepulseinthesequenatesthesample,aisabsorbed。This‘triggers’somethesystem—eleovearouom,orbondsvibrateinmoleculesorsolids。Aninstahesedpulsearrivesaisagaihesampleaed。
Asthedelaybetweewopulsesinrepeatedrunsofthisexperimeedscatteredlightmapsoutthedynamigesofthesample。Imakesa‘movie’oftheatomormoleculeorsolidasitges。This‘pump-and-probe’schemehasbeeisofens,forinstangachemicalrea,whentwomoleculesarerefiguredbytheiriioicatedversionsofthiskindofapproachexistusipulses。Theseapprusednowtoexploremauresofextremelyiingandpuzzlingmaterials,fratomsauresuperductorstobiologicalsystems。
&hattheshortestpulseitispossibletogeeisasiheopticalfield。Itturnsoutthatyoudeviseaomeasuretheossoftheopticalelectricfieldusiremeultraviolet(EUV)pulsesproducedbyhighharmoion。Whatisomeasurethepulsefieldisaveryfastproethatismuchfasterthaicalcycleitself。Thatbeprovidedbyapulsewithmuchshths,abouttwentyorthirtytimesshorterthanthatoftheopticalwavelength。Pulsesofsuchbrevityaregeedwheronisrippedoffanatombymeansopticalpulse。Thisrequiresanopticalfieldwhthisparabletothebindiheeleiucleus。Suchpulsesarereadilyavailablebyaddingopticalamplifierstotheoutputofamode-lockedlaser。
&heeleisliberatedbysutefiinginarapidlyosgelectricfield,and,ifitsliberationoearatimewhenthefieldhaszeroamplitude,theele‘surf’alocycleoftheopticalwave,takinganexawayfromtheatom,andthenba。Wheismovi,arecollideswiththeatomitberecapturedbyemittingallofitsextraenergyaslight。Inthiscaseaveryshortpulseisemittedastheelebines,haviwavelengthofperhapsafewtensofbillionthsofametre,intheEUVregiorum,abouttweerthaicalwavethatge。
NowimagihisEUVpulseshiheratom。Ithasasuffitlyshortwavelengthsuchthatitisabsorbedbytheatom,andknoele,whisitsom。Imagiheatomissimultaneouslyillumiheshortopticalpulseweseektomeasure。ThefieldofthispulseacceleratestheeleoionoranotherdependioftheopticalcycleatwhichtheeleisliberatedbytheEUVpulse。BygthedelaybetweentheEUVpulseaicalpulse,theacoftheelebemeasuredsirons,whichhavebeeree,havemy。Inthisossibleto‘see’anopticalpulsefield(Figure33),despitetheextraordinarilyshorttimescaleoftheossofthefield。
Anexampleofanappliethodsofpump-arosbiochemistryisthestudyofthefirststepsintheprocessofphotosynthesis,bywhitsverttheairintooxygenusingsunlightasanenergysource。Theprocessesbywhichthishapperanspenergyaroundabigbiologicalmoleculewithremarkablyhighefficy。Themeansbywhichthishappenshassomeveryiingandpoorlyuoodfeatures—itisfasterthaexpedmuchmoreeffit。Ifwecouldlearnfromsystemsthathaveevolvednaturallyovereonshowtodothis,perhapswouldeoapplyittothingslikeimprovingthedesignofsolarcells,whichwouldhaveanenormousimpasociety。
33。Directimageoftheelectricfieldofanopticalpulse。Thetimebeteaksisapproximately2。5fs。
Ultra-intense
Yourelectricitybilltellsyouhowmuergyyouusedinthepreviousmonth。Itismeasuredinunitsofkilowatt-hours(kWh),andyedforeaitthatyoue。Let’ssaythatyouused220kWhihisistheaveragemonthlyenergyptionintheUK)。Now,youcoulduseallthisehesamerateacrossallfourweeksofthemonth。Oryoucoulduseitiweek,ahinginthesubsequentthreeweeks。Butagiallinamillionbillionthofased?You’dohaveanawfullotofappliaousethatmuergyinsue,andyou’doswitandoffimpossiblyquickly。Butthepeakrateorpowerwouldbeimmeispossiblethtpulsesthatachievethis。Thatis,theyareincrediblybriefandthisamounty。Infact,itispossibletoproduceapulsethatdeliversearateequaltotheeygeingcapacityoftheplaagiveninstant。Butthelightsinyourhousewon’tgoout,becausethepulsesaresobriefthatthetyinthemisverysmall。
&producepulsesofthiskindaremassiveis,oglargebuildingsthatareasignifitfraofafootballfieldinsize。OheVULlaserattheRutherfordAppletonLabland。VULproducespulseswith500Joulesy(1J=kulseof500fsduration。500Jistheeedbya100Wlightbulbinfiveseds。YetthebrevityofthepulsemeansthattheiyofthelightbeashighasamillionsutheNationalIgnitionFaIF)inLivermore,uch,muchbiggerthanthis。AndtheprhtInfrastructureprojectissettodeliverasystemcapableofeveerpeakpowerthanthatatNIF。
Suchverybrief,veryiburstsbeusedtoalterstatesofmatter。Theelectricfieldatthemostiofthelightpulseislargerthaivefieldbetweeronsaholdsatomstogether。Soitispossibletostriptheelesofftheatomstoformaer—aplasma。Andit’spossibletodothisinaninstahetimeoverwhiiumove,sothattheplasmaisverydehesamedensityasinasolidbloaterialsuchasapieceofglass,exowattwomilliondegreesCelsius。
&hesihecoresofthegiasaars:veryhigh-densityplasmaswithparticlesgwitheachhspeedandatpressuresofamillioofourohere。Itispossibletousethisory-accessiblestateofmatterfs。Forinstanbegiandhohattheirlifecydtocharacterizetheirstagesofevolution,suchassupernovaeexplosionsandwhitedwarfs。Othersituatiooastrophysicistsarealsoamealexplorationusirophysicistsalsousesuchplasmastoprobethefrontiersofplaarysstaispossibletoiionofthegasgiantsfromtheirmassaoowhichmatterpressedatsuchhighpressuresisknown。
Somelaserfacilitiesgeepulsesusinglightofveryshortwavelengths。Thesepulsesareproducedbyageleaghatthey‘wiggle’fromsidetosideastheywhizdowor。ThisprodudofsynradiationgofshortburstsofX-rays。Oftenthesekindsoflasersuseteiques,andindeedhardware,fromparticleaplesofthesearetheStanfordLinearChtSource(LdtheHamburgX-rayFreeEleLaser(XFEL)。
&eiquesaffordedbythemostintenselaserpulses,inwithshortburstsofX-rays,eodiagnoseplasmasinawiderangeofs。Further,theimmensepressureexertedbylasersbetweenatomiucausethem,us,tofusetalargeamouheprocess。This‘nuclearfusion’isapossibleroutetoanalmostunlimitedsourergy。Thisapplioflasersisextremelyteicallydemanding,awomethodsthatarebeioachievefusioherdoesnotiexceptasawaytomonitortheproakeuseofdenseplasmas。
Asthelaserpulsesmhtheseplasmas,theygeeawave,verysimilartothewakethattrailsaboatmovingacrossawatersurface。Theelectricfieldsintheplasmawavereachmorethan100,000Vover10-6m(that’sabouttehevoltageinthebigpowerlinesonpyloahahofahumanhair’sbreadth。)Thesefieldstre1,000timesbiggerthaingfieldsusedinthewestmaesffuicles,suchastheLargeHadronCollider(LHimaybepossibleusihodseventuallytobuildtable-topdevicesthataccelerateeleilarenergiesastlypossibleintheLHC。
Itisalsopossibletoaccelerateheavierparticles,suearaordinarilystroricfieldsgeheiionoflaserpulsesrotonbeamsaretlybeingexploredasacertreatmehedeliveryofheavyparticlestodiseasedtissueorepredatgreaterdepthsthalypossibleusiypesofradiationtherapy。
&raordiiesoflightuetoenablenewrealmsofdiscovery,acrossawiderangeoffields。Lightisaubiquitoustoolforsdteology。